Tag Archives: chemicals

Simple method destroys dangerous ‘forever chemicals,’ making water safe

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Key takeaways:

  • World’s water tainted. Synthetic PFAS, which have been linked to cancer and other diseases, have contaminated nearly every drop of water on the planet.
  • Unbreakable bond. These chemicals contain a carbon-fluorine bond that is almost impossible to break, making it extremely difficult to eradicate them from water supplies.
  • Off with their heads! Researchers devised a “guillotine” solution that uses moderate heat and inexpensive reagents to remove the “heads” of PFAS, initiating their destruction.

If you’re despairing at recent reports that Earth’s water sources have been thoroughly infested with hazardous human-made chemicals called PFAS that can last for thousands of years, making even rainwater unsafe to drink, there’s a spot of good news.

Chemists at UCLA and Northwestern University have developed a simple way to break down almost a dozen types of these nearly indestructible “forever chemicals” at relatively low temperatures with no harmful byproducts.

Simple method destroys dangerous ‘forever chemicals,’ making water safe

Simple method destroys dangerous ‘forever chemicals,’ making water safe

In a paper published today in the journal Science, the researchers show that in water heated to just 176 to 248 degrees Fahrenheit, common, inexpensive solvents and reagents severed molecular bonds in PFAS that are among the strongest known and initiated a chemical reaction that “gradually nibbled away at the molecule” until it was gone, said UCLA distinguished research professor and co-corresponding author Kendall Houk.

The simple technology, the comparatively low temperatures and the lack of harmful byproducts mean there is no limit to how much water can be processed at once, Houk added. The technology could eventually make it easier for water treatment plants to remove PFAS from drinking water.

Per- and polyfluoroalkyl substances­ — PFAS for short — are a class of around 12,000 synthetic chemicals that have been used since the 1940s in nonstick cookware, waterproof makeup, shampoos, electronics, food packaging and countless other products. They contain a bond between carbon and fluorine atoms that nothing in nature can break.

PFAS used in shampoos

PFAS used in shampoos

When these chemicals leach into the environment through manufacturing or everyday product use, they become part of the Earth’s water cycle. Over the past 70 years, PFAS have contaminated virtually every drop of water on the planet, and their strong carbon-fluorine bond allows them to pass through most water treatment systems completely unharmed. They can accumulate in the tissues of people and animals over time and cause harm in ways that scientists are just beginning to understand. Certain cancers and thyroid diseases, for example, are associated with PFAS.

For these reasons, finding ways to remove PFAS from water has become particularly urgent. Scientists are experimenting with many remediation technologies, but most of them require extremely high temperatures, special chemicals or ultraviolet light and sometimes produce byproducts that are also harmful and require additional steps to remove.

Toxins in old toys can disrupt growth in children, an obstacle for circular economy

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Letting children play with hand-me-down plastic toys could constitute a health risk. When researchers at the University of Gothenburg tested a large number of old toys and dress-up items made of plastic, 84 per cent of the items were found to contain toxins that can disrupt growth and development and reproductive capacities in children. These toxins are an obstacle for the circular economy in the future involving reuse and recycling, the researchers explain.

The current use-and-discard behaviour is wasteful with resources and a drain on the Earth’s finite resources. In 2021, the European Parliament adopted a Circular Economy Action Plan. It encourages the re-use, repair and recycling of products and materials. But the question is whether all products are good to reuse again?

Researchers from the University of Gothenburg have recently published an article in the Journal of Hazardous Materials Advances which shows that old toys and dress-up items may contain toxic chemicals that can cause cancer, damage DNA or disrupt the future reproductive capacities of children.

plastic toys/Photo: en.wikipedia.org

Toxic chemicals in most old toys

The hazardous chemicals that were discovered included phthalates and short chain chlorinated paraffins used as plasticizers and flame retardants in toys.

Professor Bethanie Carney Almroth at the University of Gothenburg conducts research on the environmental impact of plastics and plastic-related chemicals, and has led the research study conducted at the interdisciplinary Centre for Future Chemical Risk Assessment and Management Strategies (FRAM). For the study, researchers selected 157 different toys, new and old, and measured their chemical content.

The study showed that most of the older toys and items (84 per cent) contained quantities of chemicals that exceed current legal limits. A total of 30 per cent of the newer toys and items also exceeded the legal limits. By far however, the older toys were significantly worse.

“The concentrations of toxic substances were significantly higher in the older items. For example, many of the old balls were found to have concentrations of phthalates totalling more than 40 per cent of the toy’s weight, which is 400 times over the legal limit,” says Bethanie Carney Almroth.

Many of the older toys contained toxins.

 

Toxins an obstacle to a circular economy

EU legislation on the chemical content of toys, known as the Toy Safety Directive, regulates the permissible quantities of a number of chemical substances found in toys in an attempt to protect the health and safety of children. At present, the permissible limit values for new toys under the Toy Safety Directive are 0.1 per cent by weight for phthalates and 0.15 per cent by weight for short chain chlorinated paraffins.

“The study indicates that reuse and recycling is not always automatically a good thing. The transition to a more circular economy requires bans and other policy measures that get rid of hazardous chemicals from plastic and other materials. Although the Toy Safety Directive has been crucial in reducing the incidence of hazardous chemicals in toys, it has only been applicable to new toys, not old ones,” explains Daniel Slunge, Environmental Economist at the University of Gothenburg.

Short Break from Shampoos, Lotions improve Body Health: Study

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A study led by researchers at UC Berkeley and Clinica de Salud del Valle de Salinas howed how even a short break from certain kinds of makeup, shampoos and lotions can lead to a significant drop in levels of hormone-disrupting chemicals in the body.

The results, published in the journal Environmental Health Perspectives, came from a study of 100 Latina teenagers participating in the Health and Environmental Research on Makeup of Salinas Adolescents (HERMOSA) study.

HERMOSA is a community-university collaboration between UC Berkeley, Clinica de Salud del Valle de Salinas, and a team of youth researchers from the CHAMACOS Youth Council, a project to involve young people in public health and the environment.

Researchers provided teen study participants with personal care products labeled free of chemicals such as phthalates, parabens, triclosan and oxybenzone. Such chemicals are widely used in personal care products, including cosmetics, fragrance, hair products, soaps and sunscreens, and have been shown in animal studies to interfere with the body’s endocrine system.

“Because women are the primary consumers of many personal care products, they may be disproportionately exposed to these chemicals,” said study lead author Kim Harley, associate director of the UC Berkeley Center for Environmental Research and Children’s Health. “Teen girls may be at particular risk since it’s a time of rapid reproductive development, and research has suggested that they use more personal care products per day than the average adult woman.”

Analysis of urine samples before and after a three-day trial in which the participants used the lower- chemical products found significant drops in levels of these chemicals in the body. Metabolites of diethyl phthalate, commonly used in fragrances, decreased 27 percent by the end of the trial period. Methyl and propyl parabens, used as preservatives in cosmetics, dropped 44 and 45 percent respectively. Both triclosan, found in antibacterial soaps and some brands of toothpaste, and benzophenone-3 (BP-3), found in some sunscreens under the name oxybenzone, fell 36 percent.

Surprisingly, there was a small increase in concentrations in two less common parabens. Those levels were small and could have been caused by accidental contamination or a substitution not listed on the labels, the study authors said.

Kimberly Parra, study co-director, said it was important to involve local youth in the design and implementation of the study.

“The results of the study are particularly interesting on a scientific level, but the fact that high school students led the study set a new path to engaging youth to learn about science and how it can be used to improve the health of their communities,” she said. “After learning of the results, the youth took it upon themselves to educate friends and community members, and presented their cause to legislatures in Sacramento.”

The CHAMACOS Youth Council included 12 local high school students who helped design and carry out the study. One teen researcher, Salinas native and study co-author Maritza Cárdenas, is now a UC Berkeley undergraduate majoring in molecular and cell biology.

“One of the goals of our study was to create awareness among the participants of the chemicals found in everyday products, to help make people more conscious about what they’re using,” said Cárdenas. “Seeing the drop in chemical levels after just three days shows that simple actions can be taken, such as choosing products with fewer chemicals, and make a difference.”

The researchers noted that cosmetics and personal care products are not well-regulated in this country, and that getting data about health effects from exposure, particularly long-term ones, is difficult. But they say there is growing evidence linking endocrine-disrupting chemicals to neurobehavioral problems, obesity and cancer cell growth.

“We know enough to be concerned about teen girls’ exposure to these chemicals. Sometimes it’s worth taking a precautionary approach, especially if there are easy changes people can make in the products they buy,” said Harley.

Cárdenas said the research findings have already influenced the products she buys for herself.

“Personally, since the study, I’ve tried to use more organic products,” she said. “It’s hard, especially as a college student who doesn’t have a lot of money. You tend to just get what’s on sale. But I’ve decided to splurge more on products with fewer chemicals because of the effect in the future. And if you can’t make the best choice when you’re buying because of cost, you can at least try to limit the use of the products you do buy.”